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APHA

SMWW 4500-S03 2-

Sulfite

2023

3

Standard methods for the examination of water and wastewater (543.3 APHA 24th ed. Ref. Treatises&monographs FL2)

Sulfite ions (SO3 2−) may occur in boilers and boiler feedwaters treated with sulfite for dissolved oxygen control, in natural waters or wastewaters as a result of industrial pollution, and in treatment plant effluents dechlorinated with sulfur dioxide (SO2). Excess sulfite ion in boiler waters is deleterious because it lowers the pH and promotes corrosion. Control of sulfite ion in waste­water treatment and discharge may be important environmentally, ­principally because of its toxicity to fish and other aquatic life and its rapid oxygen demand.