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ASTM

D4875-18

Standard Test Methods of Polyurethane Raw Materials: Determination of the Polymerized Ethylene Oxide Content of Polyether Polyols

2018 Vol.08.02 (2022)

7

ASTM Vol.08.02 (2022)

Test Method A—Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) measures polymerized ethylene oxide (EO) content of ethylene oxide (EO) propylene oxide (PO) polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols initiated from glycols of EO or PO containing EO percentages >5. For triols initiated with glycerol (glycerin) and trimethylolpropane, an uncorrected EO value is obtained since both initiators have protons that contribute to the EO measurement. Test Method B—Carbon-13 Nuclear Magnetic Resonance Spectroscopy (13C NMR) measures the polymerized EO content of EO-PO polyether polyols used in flexible polyurethane foams and non-foams. It is suitable for diols and triols made from the commonly used initiators and containing EO percentages >5. The values stated in SI units are to be regarded as standard.

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